157736-63-5Relevant academic research and scientific papers
Intramolecular metal-catalyzed amination of pseudo-anomeric C-H bonds
Toumieux, Sylvestre,Compain, Philippe,Martin, Olivier R.
, p. 4731 - 4735 (2007/10/03)
Intramolecular metal-catalyzed amination of a pseudo-anomeric C-H bond in a C-glycoside is reported. Treatment of α,β-C-carbamoyloxymethyl- or β-C-sulfamoyloxymethyl glycosides with Rh2(OAc)4, PhI(OAc)2, and MgO provided o
Ring-opening reactions of iminosugar-derived aziridines: Application to the general synthesis of α-1-C-substituted derivatives of fagomine
Goujon, Jean-Yves,Gueyrard, David,Compain, Philippe,Martin, Olivier R.,Asano, Naoki
, p. 1969 - 1972 (2007/10/03)
A general approach to α-1-C-substituted derivatives of fagomine (2-deoxynojirimycin-α-C-glycosides) by ring-opening reactions of an aziridine with various heteroatomic nucleophiles, including thiol, amine, alcohol, carboxylate and phosphate, is reported.
