605675-50-1

Upstream product

• 366815-71-6 (3R,4R)-1,3,4-Tris-benzyloxy-hept-6-en-2-one oxime 
• 850190-26-0 2-((1R,2R,3R)-2,3-Bis-benzyloxy-1-benzyloxymethyl-hex-5-enyl)-isoindole-1,3-dione 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 366815-69-2 (3S,4R)-1,3,4-Tris-benzyloxy-hept-6-en-2-one 
• 605675-49-8 (2S,3R,4R)-1,3,4-Tris-benzyloxy-hept-6-en-2-ol 
• 157736-63-5 (2R,3R,4R)-1,3,4-Tris-benzyloxy-hept-6-en-2-ol 
• 160549-11-1 3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranose 
• 850190-25-9 4-Nitro-benzoic acid (1S,2S,3R)-2,3-bis-benzyloxy-1-benzyloxymethyl-hex-5-enyl ester 

Downstream Products

• 850190-27-1 (2R,3R,4R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-6-iodomethyl-piperidine 
• 605675-61-4 4,5,7-tri-O-benzyl-1-O-(dibenzyloxyphosphoryl)-2,3,6-trideoxy-2,6-imino-D-manno-heptitol 
• 605675-55-6 4,5,7-tri-O-benzyl-1,2,3,6-tetradeoxy-2,6-imino-1-morpholino-D-manno-heptitol 
• 605675-58-9 1-O-benzoyl-4,5,7-tri-O-benzyl-2,3,6-trideoxy-2,6-imino-D-manno-heptitol 
• 605675-59-0 4,5,7-tri-O-benzyl-1-O-butanoyl-2,3,6-trideoxy-2,6-imino-D-manno-heptitol 
• 605675-63-6 (2R,3R,4R,6R)-3,4-di(benzyloxy)-2-benzyloxymethyl-6-ethylpiperidine 
• 366815-73-8 ((1R,2R,3R)-2,3-Bis-benzyloxy-1-benzyloxymethyl-hex-5-enyl)-carbamic acid 9H-fluoren-9-ylmethyl ester 
• 366815-82-9 ((1S,2R,3R)-2,3-Bis-benzyloxy-1-benzyloxymethyl-hex-5-enyl)-carbamic acid 9H-fluoren-9-ylmethyl ester 

Relevant academic research and scientific papers

Ring-opening reactions of iminosugar-derived aziridines: Application to the general synthesis of α-1-C-substituted derivatives of fagomine

A general approach to α-1-C-substituted derivatives of fagomine (2-deoxynojirimycin-α-C-glycosides) by ring-opening reactions of an aziridine with various heteroatomic nucleophiles, including thiol, amine, alcohol, carboxylate and phosphate, is reported.

Chemistry of imino glycals: Preparation and application to the synthesis of (+)-fagomine

The synthesis of imino glucal 2 from tri-O-benzyl-D-glucal in 8 steps is described. This novel imino sugar building block is further converted into (+)-fagomine by a two-step hydrogenation sequence.