15775-45-8Relevant academic research and scientific papers
Palladium-catalyzed synthesis of substituted cycloheptane-1,4-diones by an asymmetric ring-expanding allylation (AREA)
Schulz, Sabrina R.,Blechert, Siegfried
, p. 3966 - 3970 (2007)
(Chemical Equation Presented) The right AREA: Functionalized, seven-and eight-membered carbocycles are available from an asymmetric Pd-catalyzed decarboxylative fragmentation of strained bicyclo[3.2.0]heptane-2-ones (see scheme, dba = trans,trans-dibenzylidene-acetone). The products were formed in a sequence of [2+2] cycloaddition, retro-aldol reaction, and asymmetric allylation of ketone enolates.
