15781-34-7

Upstream product

• 108233-75-6 allyl (1SR,5SR)-5-(tert-butyl)-1-methyl-2-oxocyclohexane-1-carboxylate 
• 108233-75-6 allyl (1RS,5SR)-5-(tert-butyl)-1-methyl-2-oxocyclohexane-1-carboxylate 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 108233-77-8 allyl 5-tert-butyl-2-oxocyclohexanecarboxylate 
• 3211-27-6 4-tert-butyl-2-methylcyclohexanone 
• 106-95-6 allyl bromide 
• 5064-52-8 2-methyl-4-tert-butylcyclohexanone 
• 86137-08-8 5-tert-Butyl-2-hydroxy-3-methyl-cyclohex-2-enone 
• 40571-96-8 ethyl 5-(tert-butyl)-2-oxocyclohexanecarboxylate 
• 13019-03-9 trans-2-Aethoxycarbonyl-2-methyl-4-tert.-butyl-cyclohexanon 
• 15839-52-8 (5-tert-butyl-2-oxo-cyclohexyl)-oxo-acetic acid ethyl ester 
• 86137-11-3 (4R,6R)-6-Allyl-4-tert-butyl-2-hydroxy-6-methyl-cyclohex-2-enone 
• 86137-13-5 4-Phenyl-piperidine-1-carbothioic acid O-((3R,5R)-5-allyl-3-tert-butyl-5-methyl-6-oxo-cyclohex-1-enyl) ester 
• 86137-07-7 2,6-Dibromo-4-tert-butyl-2-methyl-cyclohexanone 

Downstream Products

• 1610601-75-6 (E)-2-((2R,4R)-2-allyl-4-(tert-butyl)-2-methylcyclohexylidene)-N-((1S,2S,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)hydrazine-1-carboxamide 
• 1610601-73-4 (E)-2-((2R,4R)-2-allyl-4-(tert-butyl)-2-methylcyclohexylidene)hydrazine-1-carboxamide 

Relevant academic research and scientific papers

Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters

The palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters derived from 4-tert-butylcyclohexanone is described. These experiments were performed to elucidate our understanding of stereoablative enantioconvergent catalysis. A

AXIAL ALLYLATION ON THE DIOSPHENOL CLAISEN REARRANGEMENT

A 5:1 preference for axial vs. equatorial allylation is shown in the Claisen rearrangement of the conformationally-rigid diosphenol allyl ether l.