108233-75-6

Upstream product

• 98-53-3 4-tercbutyl-cyclohexanone 
• 2484-72-2 methyl 5-tert-butyl-2-oxocyclohexanecarboxylate 
• 108233-77-8 allyl 5-tert-butyl-2-oxocyclohexanecarboxylate 
• 74-88-4 methyl iodide 

Downstream Products

• 15781-34-7 cis-(2R,4R)-2-allyl-4-(tert-butyl)-2-methylcyclohexan-1-one 
• 15781-34-7 trans-(2S,4R)-2-allyl-4-(tert-butyl)-2-methylcyclohexan-1-one 
• 1610601-70-1 trans-(2R,4S)-2-allyl-4-(tert-butyl)-2-methylcyclohexan-1-one 
• 1610601-74-5 (E)-2-((2R,4S)-2-allyl-4-(tert-butyl)-2-methylcyclohexyl-idene)-N-((1S,2S,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)hydrazine-1-carboxamide 
• 1610601-75-6 (E)-2-((2R,4R)-2-allyl-4-(tert-butyl)-2-methylcyclohexylidene)-N-((1S,2S,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)hydrazine-1-carboxamide 
• 87373-11-3 (1SR,2SR,4SR)-4-(tert-butyl)-2-(hydroxymethyl)-2-methylcyclohexan-1-ol 
• 1610601-72-3 (E)-2-((2R,4S)-2-allyl-4-(tert-butyl)-2-methylcyclohexylidene)hydrazine-1-carboxamide 
• 1610601-73-4 (E)-2-((2R,4R)-2-allyl-4-(tert-butyl)-2-methylcyclohexylidene)hydrazine-1-carboxamide 
• 15781-34-7 trans-2-allyl-4-(tert-butyl)-2-methylcyclohexan-1-one 
• 87373-09-9 (1SR,2RS,4SR)-4-(tert-butyl)-2-(hydroxymethyl)-2-methylcyclohexan-1-ol 

Relevant academic research and scientific papers

Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters

The palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters derived from 4-tert-butylcyclohexanone is described. These experiments were performed to elucidate our understanding of stereoablative enantioconvergent catalysis. A

Palladium-Catalyzed Decarboxylation-Allylation of Allylic Esters of α-Substituted β-Keto Carboxylic, Malonic, Cyanoacetic, and Nitroacetic Acids

Decarboxylation-allylation of allylic β-keto carboxylates using Pd(OAc)2-PPh3 or Pd2(dba)3*CHCl3-dppe as a catalyst proceeds smoothly to give α-allylated ketones.The reaction is highly regioselective.In some cases, diallylated ketones are obtained with allylic esters bearing an active proton(s).Also rhodium, molybdenum, and nickel complexes sre active catalysts in this reaction.Similarly allylic esters of α-substituted malonates, cyanoacetates, and nitroacetate undergo the palladium-catalyzed decarboxylation-allylation to afford allylated acetate, acetonitrile, and nitromethane, respectively.The mechanisms of these palladium-cataly zed decarboxylation-allylations are discussed