15786-26-2

Usage

Uses

Used in Polymer and Resin Production:
(1Z,3E)-cyclododeca-1,3-diene-1,2-diol is used as a monomer in the production of polymers and resins, contributing to the development of materials with specific properties tailored for various applications.
Used in Organic Synthesis:
(1Z,3E)-cyclododeca-1,3-diene-1,2-diol serves as a key intermediate in the synthesis of various organic compounds, enabling the creation of a wide range of chemical products.
Used in Pharmaceutical and Medicinal Applications:
(1Z,3E)-cyclododeca-1,3-diene-1,2-diol is used as a starting material or intermediate in the development of pharmaceuticals and medicines, potentially leading to new treatments and therapies.
Used in Research and Development:
Due to its unique structure and properties, (1Z,3E)-cyclododeca-1,3-diene-1,2-diol is utilized in research and development efforts across various industries, driving innovation and the discovery of new applications.

Upstream product

• 60391-93-7 (4E,8E)-dodeca-4,8-dienedial 
• 676-22-2 (1E,5E,9E)-cyclododeca-1,5,9-triene 
• 706-31-0 (1E,5E,9Z)-cyclododeca-1,5,9-triene 

Downstream Products

• 60391-93-7 (4E,8E)-dodeca-4,8-dienedial 
• 693-23-2 1,12-dodecanedioic acid 
• 97424-03-8 (Z)-4-dodecene-1,12-diacid 
• 15786-31-9 diethyl hexadecanedioate 
• 28079-04-1 (Z)-8-dodecen-1-yl acetate 
• 40642-40-8 (Z)-8-dodecenol 
• 15786-37-5 dodeca-4c,8t-dienedial 
• 55303-96-3 dodeca-4,8-diene-1,12-dialdehyde 

Relevant academic research and scientific papers

Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin

Two concise syntheses of the natural products cis-sylvaticin and sylvaticin are reported, using oxidative cyclization methodology as the key step. A sequential solvolysis/hydride shift/intramolecular reduction cascade was used to establish the trans stereochemistry of one of the THF rings of sylvaticin.

Asymmetric dihydroxylation affords enantiomerically pure c12 building blocks from trans,trans,cis-1,5,9-cyclododecatriene

Through sequential catalytic asymmetric dihydroxylation (AD), t,t,c-1,5,9-cyclododecatriene is transformed into functionalized cyclic cis-olefins with high enantio- and diastereocontrol. To demonstrate their synthetic utility as sources for open chain C12 building blocks, one such intermediate is converted into an α,ω-diester in which the chain ends are differentiated.

Selective Asymmetric Dihyroxylation of Polyenes

The asymmetric dihydroxylation procedure (AD) is applied to a variety of polyenes.In many cases excellent regioselectivities are obtained.The observed selectivities are rationalized in terms of electronic and/or steric inherent to the substrate, superimposed on the substrate's favorable or unfavorable interactions with the binding pocket of the AD ligand.Surprisingly, for medium and large ring olefins with trans-double bonds outstanding enantioselectivities are realized using the pyrimidine ligands.A hexaol of D3 symmetry is prepared from all trans cyclodecatriene.

SYNTHESIS OF 1,2-CYCLOALKANEDIOLS BY INTRAMOLECULAR TITANIUM-INDUCED PINACOL COUPLING

Seven representative 1,2-cycloalkanediols of ring size 6-14 were prepared in high yield by titanium-induced pinacol coupling of dialdehydes.Cis stereochemistry predominated in six- and eight-membered rings, but trans products were formed in ring sizes ten and above.