15787-87-8Relevant academic research and scientific papers
Synthesis of the naphthalenone, dihydroquinoline, and dihydrofuran derivatives
Guengoer, Fuesun Seyma,Anac, Olcay,Sezer, Oezkan
, p. 1115 - 1129 (2011/08/05)
The reactions of enaminones with dimethyl diazomalonate were investigated in the presence of copper(II) acetylacetonate. From the reaction of (E)-3-[methyl(phenyl)amino]-1-phenylprop-2-en-1-one (6c), dimethyl 2-[methyl(phenyl)amino]-4-oxonaphthalene-1,1-(4H)-dicarboxylate, was unexpectedly obtained as the major product. Quinoline derivatives were formed as the major products in the case of N-methyl-p-anisidino and N-methyl-p-toluidino enaminones. The reactions of acetyl enaminones were also realized, and quinoline derivatives were isolated as the major products. 3H- and 5H-dihydrofurans were also formed as side products in these reactions. These results differ from those reported earlier on the reactions of tertiary enaminones with carbenes/metal carbenes.
Doubly Vinylogous 4H-Pyrones from Pyrylium Salts and Aryl β-Chlorovinyl Ketones
Balaban, Alexandru T.,Fahmy, Mahmoud,Gheorghiu, Mircea D.,Wray, Victor
, p. 1807 - 1817 (2007/10/02)
Aryl β-chlorovinyl ketones react with the methyl group of 2,6-di-tert-butyl-4-methylpyrylium perchlorate in the presence of pyridine to yield doubly vinylogous 4H-pyrones 3.Only one configuration and conformation from the eight possible structures appears
