157918-38-2

Upstream product

• 14470-28-1 mono-4-methoxytrityl chloride 
• 157918-31-5 methyl (2E,4S)-4-<<(tert-butyl)dimethylsilyl>oxy>-6-<(4-methoxyphenyl)(diphenyl)methoxy>hex-2-eneoate 
• 157918-33-7 (2E,4S)-4-<<(tert-butyl)dimethylsilyl>oxy>-6-<(4-methoxyphenyl)(diphenyl)methoxy>hex-2-en-1-ol 
• 109462-36-4 methyl (2E,4S)-4-<<(tert-butyl)dimethylsilyl>oxy>-6-hydroxyhex-2-eneoate 
• 3282-30-2 pivaloyl chloride 
• 157918-36-0 (2S,4S)-4-<<(tert-butyl)dimethylsilyl>oxy>-6-<(4-methoxyphenyl)(diphenyl)methoxy>hexane-1,2-diol 

Relevant academic research and scientific papers

Studies directed towards the synthesis of phomenoic acid. Part 1. Enantioselective synthesis of the C(1)-to-C(6) segment

Based on a retrosynthetic analysis, a concept for the synthesis of all stereoisomers of the C(1)-to-C(6) segment of phomenoic acid has been developed. Both enantiomers of the chiral synthon 9 were prepared starting from rac-epoxy-diester 10. They were con