1579197-75-3Relevant academic research and scientific papers
An unexpected rearrangement of pent-4-enofuranosides to cyclopentanones upon hydrogenolysis of the anomeric benzyl group
Nie, Shenyou,Chen, Xiaoping,Ma, Yuyong,Li, Wei,Yu, Biao
, p. 36 - 40 (2016/07/07)
During our synthesis toward the unique nucleoside antibiotic A201A, we were surprised to find that a benzyl arabino-pent-4-enofuranoside underwent a Ferrier II-like rearrangement readily to provide the corresponding cyclopentanone derivative in high yield and stereoselectivity upon hydrogenolysis of the anomeric benzyl group.
Total synthesis of nucleoside antibiotic A201A
Nie, Shenyou,Li, Wei,Yu, Biao
supporting information, p. 4157 - 4160 (2014/04/03)
A201A, a unique nucleoside antibiotic with potent antibacterial activities, has been synthesized for the first time in a total of 47 steps in a highly modular and linear manner, highlighting the elaboration/incorporation of an unprecedented hexofuranoside unit bearing an exocyclic enol ether moiety.
