1579249-56-1

Basic information

• Product Name: (S)-3-(3-methoxyphenyl)-3-phenyl-1-butene
• Synonyms: (S)-3-(3-methoxyphenyl)-3-phenyl-1-butene
• CAS NO: 1579249-56-1
• Molecular Weight: 238.329
• Mol File: 1579249-56-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-3-(3-methoxyphenyl)-3-phenyl-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-(3-methoxyphenyl)-3-phenyl-1-butene(1579249-56-1)
• EPA Substance Registry System: (S)-3-(3-methoxyphenyl)-3-phenyl-1-butene(1579249-56-1)

Safety Data

• Hazardous Substances Data: 1579249-56-1(Hazardous Substances Data)

Upstream product

• 1003858-50-1 2-(3-methoxyphenyl)-5, 5-dimethyl-1,3,2-dioxaborinane 
• 768392-43-4 (E)-diethyl (3-phenylbut-2-en-1-yl) phosphate 

Downstream Products

• 1579249-63-0 (S)-3-(3-methoxyphenyl)-3-phenyl-1-butanol 

Relevant articles and documents

Synthesis of quaternary carbon stereocenters by copper-catalyzed asymmetric allylic substitution of allyl phosphates with arylboronates

A copper-catalyzed asymmetric allylic substitution of γ,γ- disubstituted allyl phosphates with arylboronates has been developed for the construction of quaternary stereocenters. High regio- and enantioselectivities have been achieved by employing a hydroxy-bearing chiral N-heterocyclic carbene ligand, and both E and Z substrates provide the same enantiomer as the major product. The mechanistic aspect of this catalysis has also been investigated to find that a 1:1 copper/ligand complex is most likely responsible for the present asymmetric catalysis, and the reaction proceeds with almost perfect 1,3-anti stereochemistry with respect to the allylic electrophile.