157992-80-8Relevant academic research and scientific papers
2,3-Disubstituted tetrahydrofuran synthesis via radical and anionic cyclization
Burke, Steven D.,Jung, Kyung Woon
, p. 5837 - 5840 (1994)
Cyclization of the radicals derived from C-S bond homolysis as well as via 1,5-hydrogen atom transfer afforded tetrahydrofurans in high yield. An alternative anionic cyclization method provided the anti diastereomer preferentially.
Air Oxidative Radical Oxysulfurization of Alkynes Leading to α-Thioaldehydes
Zhou, Shao-Fang,Pan, Xiang-Qiang,Zhou, Zhi-Hao,Shoberu, Adedamola,Zhang, Pei-Zhi,Zou, Jian-Ping
supporting information, p. 5348 - 5354 (2015/05/27)
Air oxidative radical oxysulfurization of alkynes initiated by 0.5 mol % tert-butyl hydroperoxide with arylthiols is described. The reaction proceeded at room temperature in the presence of 5% mol water to afford selective α-thioaldehydes. (Chemical Equation Presented).
A short route to avenaciolide & isoavenaciolide via radical cyclization
Burke, Steven D.,Jung, Kyung Woon,Perri, Roman E.
, p. 5841 - 5844 (2007/10/02)
The bicyclic ether/lactone 5 was prepared from 7 in 6 steps including radical cyclization and a Pummerer rearrangement. After 5 was converted to 12 and 13 under Keek's conditions, divergent formal total syntheses of avenaciolide and isoavenaciolide were a
