158012-86-3Relevant academic research and scientific papers
Efficient Route to Highly Functionalized Tetrahydrofurans by Stereocontrolled Silicon-directed Cyclization
Delft, F. L. van,Marel, G. A. van der,Boom, J. H. van
, p. 339 - 341 (1994)
Cyclization of 3,4,6-tri-O-benzyl-2,5-di-O-trimethylsilyl-1-deoxy-1-phenyldiisopropylsilyl-L-glucitol in the presence of BF3*Et2O or catalytic H2SO4 proceeds stereoselectively to give predominantly the fully benzylated 2,5-anhydro-L-glucitol derivative without occurrence of the Peterson elimination.
