1581756-75-3Relevant articles and documents
Ortho–C–H amidations enabled by a recyclable manganese-ionic liquid catalytic system
Kong, Xianqiang,Xu, Bo
supporting information, (2019/12/27)
We described an environmentally benign, recyclable base metal catalyst system (MnBr(CO)5/[Hmim]OAc) for ortho–C–H amidation. The readily available dioxazolones was used as the amidation agents. A broad substrate scope and high functional group
Rhodium-Catalyzed C?H Activation Enabled by an Indium Metalloligand
Yamada, Ryosuke,Iwasawa, Nobuharu,Takaya, Jun
supporting information, p. 17251 - 17254 (2019/11/13)
Rhodium complexes with an indium metalloligand were successfully synthesized by utilizing a pyridine-tethered cyclopentadienyl ligand as a support for an In?Rh bond. The indium metalloligand dramatically changes the electronic and redox properties of the
Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C-H Amination with a New Type of Amidating Reagent
Park, Yoonsu,Park, Kyung Tae,Kim, Jeung Gon,Chang, Sukbok
supporting information, p. 4534 - 4542 (2015/04/22)
Mechanistic investigations on the CpRh(III)-catalyzed direct C-H amination reaction led us to reveal the new utility of 1,4,2-dioxazol-5-one and its derivatives as highly efficient amino sources. Stepwise analysis on the C-N bond-forming process showed th