1582780-99-1

Basic information

• Product Name: methyl 1-benzoyl-1,1a,6,6a-tetrahydrocyclopropa[a]-indene-1-carboxylate
• Synonyms: methyl 1-benzoyl-1,1a,6,6a-tetrahydrocyclopropa[a]-indene-1-carboxylate
• CAS NO: 1582780-99-1
• Molecular Weight: 292.334
• Mol File: 1582780-99-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 1-benzoyl-1,1a,6,6a-tetrahydrocyclopropa[a]-indene-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 1-benzoyl-1,1a,6,6a-tetrahydrocyclopropa[a]-indene-1-carboxylate(1582780-99-1)
• EPA Substance Registry System: methyl 1-benzoyl-1,1a,6,6a-tetrahydrocyclopropa[a]-indene-1-carboxylate(1582780-99-1)

Safety Data

• Hazardous Substances Data: 1582780-99-1(Hazardous Substances Data)

Upstream product

• 1807-69-8 2-diazo-3-oxo-3-phenyl-propionic acid methyl ester 
• 95-13-6 1-indene 

Relevant articles and documents

Functionalized 4-carboxy- and 4-keto-2,3-dihydropyrroles via Ni(II)-catalyzed nucleophilic amine ring-opening cyclizations of cyclopropanes

A general synthetic approach to vinylogous 4-carboxy- and 4-keto-2,3-dihydropyrroles is reported using Ni(ClO4) 26H2O as a Lewis acid catalyst for nucleophilic amine ring-opening cyclizations of donor-acceptor (D-A) cyclopropanes. This methodology provided good to excellent yields of functionalized 2,3-dihydropyrroles under milder reaction conditions than previously reported and is amenable to a variety of D-A cyclopropanes and primary amines.