1807-69-8

Basic information

• Product Name: [2-methoxy-2-oxo-1-(phenylcarbonyl)ethylidene]diazenium
• CAS NO: 1807-69-8
• Molecular Formula: C₁₀H₈N₂O₃
• Molecular Weight: 205.1895
• Mol File: 1807-69-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: [2-methoxy-2-oxo-1-(phenylcarbonyl)ethylidene]diazenium(CAS DataBase Reference)
• NIST Chemistry Reference: [2-methoxy-2-oxo-1-(phenylcarbonyl)ethylidene]diazenium(1807-69-8)
• EPA Substance Registry System: [2-methoxy-2-oxo-1-(phenylcarbonyl)ethylidene]diazenium(1807-69-8)

Safety Data

• Hazardous Substances Data: 1807-69-8(Hazardous Substances Data)

Usage

General Description

[2-methoxy-2-oxo-1-(phenylcarbonyl)ethylidene]diazenium is a chemical compound with the chemical formula C10H10N2O3. It is a diazeniumdiolate derivative that has been studied for its potential use in many medical and scientific applications. [2-methoxy-2-oxo-1-(phenylcarbonyl)ethylidene]diazenium is known to have anti-inflammatory, anti-cancer, and antibacterial properties. It has been shown to inhibit the growth of various cancer cells and exhibit potential as a therapeutic agent in the treatment of inflammatory diseases and bacterial infections. Further research is necessary to fully understand the potential uses and effects of this compound, but it shows promise as a versatile and valuable chemical in the field of medicine and biochemistry.

Upstream product

• 941-55-9 4-toluenesulfonyl azide 
• 614-27-7 methyl 3-oxo-3-phenylpropionate 
• 98-86-2 acetophenone 
• 110996-38-8 2-hydroxyimino-3-oxo-3-phenyl-propionic acid methyl ester 
• 618-32-6 Benzoyl bromide 
• 6832-16-2 methyl diazoacetate 
• 98-88-4 benzoyl chloride 

Downstream Products

• 4874-87-7 methyl 1,5-diphenyl-1H-1,2,3-triazole-4-carboxylate 
• 2613-89-0 phenylmalonic acid 
• 38114-29-3 erythro-methyl 2-amino-3-hydroxy-3-phenylpropanoate 
• 1582780-95-7 methyl 1-benzoyl-2-(4-nitrophenyl)cyclopropane-1-carboxylate 
• 1582781-20-1 methyl 1-benzyl-5-methyl-2,5-diphenyl-4,5-dihydro-1H-pyrrole-3-carboxylate 
• 1582780-99-1 methyl 1-benzoyl-1,1a,6,6a-tetrahydrocyclopropa[a]-indene-1-carboxylate 
• 1582781-22-3 methyl 1-benzyl-4-methyl-2,5-diphenyl-4,5-dihydro-1H-pyrrole-3-carboxylate 
• 1582781-00-7 methyl 1-benzoyl-2-methyl-3-phenylcyclopropane-1-carboxylate 
• 1403871-53-3 methyl (2E)-2-bromo-3-(1-methoxy-1,3-dioxo-3-phenylpropan-2-ylideneamino)-3-phenylacrylate 

Relevant articles and documents

Iridium(III)-Catalyzed C(3)-H Alkylation of Isoquinolines via Metal Carbene Migratory Insertion

An Ir(III)-catalyzed C(3)-H alkylation of N-acetyl-1,2-dihydroisoquinolines with diverse acceptor-acceptor diazo compounds has been achieved under a single catalytic system via metal carbene migratory insertion. Moreover, further synthetic transformations of the alkylated products such as aromatization, selective decarboxylation, and decarbonylation lead to the formation of several synthetically viable isoquinoline derivatives having immense potentials.

One-pot synthesis of β-O-4 lignin models: Via the insertion of stable 2-diazo-1,3-dicarbonyls into O-H bonds

Because lignin is a macromolecule that is a sustainable source of aromatic compounds, model substrates are commonly used to increase our understanding of its complex structure. However, few methods have been described for the synthesis of these models. Herein, we describe a new route towards the synthesis of β-O-4 lignin models by intermolecular O-H insertion reactions with simple and stable diazocarbonyls. The benefits of this developed method were shorter reaction times and high yields, as well as mild and environmentally friendly conditions. This journal is

One-pot synthesis of 2,3-difunctionalized indoles: Via Rh(III)-catalyzed carbenoid insertion C-H activation/cyclization

Reported herein is the first Rh(iii)-catalyzed carbenoid insertion C-H activation/cyclization of N-arylureas and α-diazo β-keto esters. The redox-neutral reaction has the following features: good to excellent yields, broad substrate/functional group tolerance, exclusive regioselectivity, and no need for additional oxidants or additives, which render this methodology as a more efficient and versatile alternative to the existing methods for the synthesis of 2,3-difunctionalized indoles.