1584667-75-3

Upstream product

• 941-55-9 4-toluenesulfonyl azide 
• 1584667-71-9 (E)-1,2-bis(3-(trifluoromethyl)phenyl)diazene 
• 51437-67-3 trans-3,3'-dimethylazobenzene 
• 73901-01-6 p-nitrobenzenesulfonyl azide 
• 108-44-1 1-amino-3-methylbenzene 

Downstream Products

• 107920-89-8 5-methyl-2-(m-tolyl)-2H-benzo[d][1,2,3]triazole 

Relevant academic research and scientific papers

Synthesis of 2-Aryl-2 H-benzotrizoles from azobenzenes and N-sulfonyl azides through sequential rhodium-catalyzed amidation and oxidation in one pot

An efficient synthetic method of 2-aryl-2H-benzotriazoles from nonprefunctionalized azobenzenes and N-sulfonyl azides via sequential Rh-catalyzed amidation (C-N bond formation) and oxidation (N-N bond formation) with PhI(OAc)2 in one pot is reported.

Rhodium-catalyzed direct ortho C-N bond formation of aromatic Azo compounds with azides

An efficient rhodium-catalyzed regioselective C-N bond formation of azo compounds in good to excellent yields through C-H bond functionalization using azides as the nitrogen source was developed. Alkyl, aryl, and sulfonyl azides could be efficiently assem