1584705-69-0Relevant articles and documents
(Pentamethylcyclopentadienyl)cobalt(III)-Catalyzed Direct Trifluoromethylthiolation of Arenes via C?H Activation
Liu, Xu-Ge,Li, Qingjiang,Wang, Honggen
supporting information, p. 1942 - 1946 (2017/06/09)
The direct trifluoromethylthiolation of arenes was realized via (pentamethylcyclopentadienyl)cobalt(III)-catalyzed C(sp2)-H activation and coupling with AgSCF3 under the assistance of a directing group. The reaction features redox-neutrality, mild conditions, broad substrate scope, and good functional group tolerance. Preliminary mechanistic studies have been conducted. (Figure presented.).
