158497-99-5

Upstream product

• 95514-03-7 (R)-methyl 3-(tert-butyl(diphenyl)silyloxy)-2-methylpropanoate 
• 158497-97-3 (Z)-(3R,4S,7S,8R)-9-(tert-Butyl-diphenyl-silanyloxy)-7-hydroxy-3-(4-methoxy-benzyloxy)-4,8-dimethyl-non-5-enoic acid 
• 158497-95-1 Acetic acid (Z)-(1S,4S,5R)-1-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-7-hydroxy-5-(4-methoxy-benzyloxy)-4-methyl-hept-2-enyl ester 
• 158497-96-2 (Z)-(3R,4S,7S,8R)-7-Acetoxy-9-(tert-butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-4,8-dimethyl-non-5-enoic acid 
• 158497-93-9 C₃₅H₃₅IO₄ 
• 158497-92-8 C₃₅H₃₆O₄ 
• 158497-91-7 (2S,3R)-3-(4-Methoxy-benzyloxy)-5-[(4-methoxy-phenyl)-diphenyl-methoxy]-2-methyl-pentan-1-ol 
• 412908-78-2 (3R,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-4-methyl-pentan-1-ol 
• 158497-90-6 tert-Butyl-[(2S,3R)-3-(4-methoxy-benzyloxy)-2-methyl-pent-4-enyloxy]-diphenyl-silane 
• 1026876-62-9 (3R,4S)-4-Methyl-5-(tetrahydro-pyran-2-yloxy)-pent-1-en-3-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 95514-04-8 (S)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 
• 91751-24-5 (R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal 
• 170808-37-4 (3R,4S,7S,8R)-9-(tert-Butyl-diphenyl-silanyloxy)-7-hydroxy-3-(4-methoxy-benzyloxy)-4,8-dimethyl-nonanoic acid 

Downstream Products

• 158498-00-1 (4R,5S,8S)-8-((R)-2-Hydroxy-1-methyl-ethyl)-4-(4-methoxy-benzyloxy)-5-methyl-oxocan-2-one 
• 1041782-40-4 (S)-2-[(2S,5S,6R)-6-(4-Methoxy-benzyloxy)-5-methyl-8-oxo-oxocan-2-yl]-propionaldehyde 
• 158498-04-5 (4R,5S,8S)-8-((S)-2-{(2S,3R)-3-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-butyl]-2-methyl-oxiranyl}-1-methyl-2-oxo-ethyl)-4-(4-methoxy-benzyloxy)-5-methyl-oxocan-2-one 
• 158498-02-3 (4R,5S,8S)-8-[(E)-(1R,2R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-1,3,7-trimethyl-oct-3-enyl]-4-(4-methoxy-benzyloxy)-5-methyl-oxocan-2-one 
• 158569-56-3 (4R,5S,8S)-8-[(E)-(1R,2S,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-1,3,7-trimethyl-oct-3-enyl]-4-(4-methoxy-benzyloxy)-5-methyl-oxocan-2-one 

Relevant academic research and scientific papers

An Improved Synthesis of the Octalactins

A new and efficient synthesis of the key C.1-C.9 intermediate 5 of the octalactins has been achieved starting from L-ascorbic acid.

Facile synthesis of saturated eight-membered ring lactones

The synthesis of functionalized saturated eight-membered ring lactones from their corresponding seco acids is a very facile process using conventional macrolactonization protocols. This heretofore unrecognized and overlooked strategy is illustrated for se