158548-98-2

Upstream product

• 147425-36-3 Methyl 4-amino-3-O-benzoyl-2-O-benzyl-4,6-dideoxy-N-(ethoxycarbonyl)-α-D-galactopyranoside 
• 147425-40-9 (1'S,2'R,4S,5R)-4-<2'-(Benzyloxy)-1'-<(tert-butyldimethylsilyl)oxy>-3'-oxopropyl>-3-(tert-butyldimethylsilyl)-5-methyl-2-oxazolidinone 
• 147425-37-4 Benzoic acid (3R,4S,5S,6R)-3-benzyloxy-5-ethoxycarbonylamino-2-hydroxy-6-methyl-tetrahydro-pyran-4-yl ester 
• 147425-39-6 (1'S,2'R,4S,5R)-4-<2'-(Benzyloxy)-1'-<(tert-butyldimethylsilyl)oxy>-3'-hydroxypropyl>-3-(tert-butyldimethylsilyl)-5-methyl-2-oxazolidinone 
• 147425-48-7 Methyl 3-O-benzoyl-2-O-benzyl-6-deoxy-4-O-(methanesulfonyl)-α-D-glucopyranoside 
• 147425-35-2 Methyl 4-azido-3-O-benzoyl-2-O-benzyl-4,6-dideoxy-α-D-galactopyranoside 
• 147425-46-5 methyl 3‐O‐benzoyl‐2‐O‐benzyl‐α‐D-glucopyranoside 
• 158548-94-8 [(1S,2S,3S)-3-Benzyloxy-2,4-dihydroxy-1-((R)-1-hydroxy-ethyl)-butyl]-carbamic acid ethyl ester 
• 147425-38-5 (1'S,2'S,4R,5R)-4-<2'-(Benzyloxy)-1',3'-dihydropropyl>-5-methyl-2-oxazolidinone 
• 76375-66-1 methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 147425-42-1 (4S,5R)-3-(tert-Butyl-dimethyl-silanyl)-4-[(1S,2S,3R)-1-(tert-butyl-dimethyl-silanyloxy)-2,3-dihydroxy-5-phenylsulfanylmethyl-hex-5-enyl]-5-methyl-oxazolidin-2-one 
• 77-76-9 2,2-dimethoxy-propane 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 147425-47-6 Methyl 3-O-benzoyl-2-O-benzyl-4,6-bis-O-(methanesulfonyl)-α-D-glucopyranoside 

Downstream Products

• 147425-45-4 (1'R,2'S,3'R,4S,5R)-4-<5'-Oxo-2',3'-(2-propylidenedioxy)cyclohexyl>-5-methyl-3-<(4-methylphenyl)methanesulfonyl>-2-oxazolidinone 
• 158549-02-1 (1'R,2'S,3'R,4S,5R)-4-<5'-Methylidene-2',3'-(2-propylidenedioxy)cyclohexyl>-5-methyl-3-<(4-methylphenyl)methanesulfonyl>-2-oxazolidinone 
• 147514-08-7 5,6-O-(2-Propylidene)-N-desalanyl-N-<(4-methylphenyl)methanesulfonyl>actinobolin 
• 147425-43-2 (1'S,2'S,3'R,4S,5R)-3,1'-O-(Thiocarbonyl)-4-<1'-hydroxy-5'-<(phenylthio)methyl>-2',3'-(2-propylidenedioxy)-5'-hexenyl>-5-methyl-2-oxazolidinone 
• 126423-73-2 (1'S,2'R,3'R,4S,5R)-5-<2'-Hydroxy-1'-<(4-methylphenyl)methanesulfonamido>propyl>-3,4-(2-propylidenedioxy)cyclohexanone 
• 158548-99-3 (4R,5R)-4-{(S)-[(4R,5R)-2,2-Dimethyl-5-(2-phenylsulfanylmethyl-allyl)-[1,3]dioxolan-4-yl]-hydroxy-methyl}-5-methyl-oxazolidin-2-one 

Relevant academic research and scientific papers

The diastereoselective synthesis of (+)-actinobolin from D-glucose

The carbocyclic ring of actinobolin was constructed by a [3 + 3] annulation of a D-galactosamine derivative with 3-phenylthio-2-(trimethylsilylmethyl)propene. Formation of the lactone and acylation with L-alanine according to literature precedent gave (+)