158598-32-4Relevant academic research and scientific papers
Chemoselective alkylation of L-ascorbic acid
Kulkarni, Mukund G.,Thopate, Shankar R.
, p. 1293 - 1302 (1996)
A study on a general chemoselective method for the preparation of 3-O-alkyl and differentially protected 2,3-di-O-alkyl derivatives of 5,6-O-isopropylidene-L-ascorbic acid is described.
Chemistry of L-Ascorbic Acid: Regioselective and Stereocontrolled 2-C- and 3-C-Allylation via Thermal Claisen Rearrangement
Wimalasena, Kandatege,Mahindaratne, Mathew P. D.
, p. 3427 - 3432 (2007/10/02)
We report the convenient preparation of 3-O- and 2-O-allylated derivatives of 5,6-O-isopropylidene-L-ascorbic acid (1) with various allyl substituents in high yield and their quantitative thermal Claisen rearrangement to the corresponding 2-C- and 3-C-all
