158678-12-7

Basic information

• Product Name: (1-acetyl-2-methyl-3-cyclohexen-4-yl)pyridinebis(dimethylglyoximato)cobalt(III)
• CAS NO: 158678-12-7
• Molecular Weight: 505.52
• Mol File: 158678-12-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1-acetyl-2-methyl-3-cyclohexen-4-yl)pyridinebis(dimethylglyoximato)cobalt(III)(CAS DataBase Reference)
• NIST Chemistry Reference: (1-acetyl-2-methyl-3-cyclohexen-4-yl)pyridinebis(dimethylglyoximato)cobalt(III)(158678-12-7)
• EPA Substance Registry System: (1-acetyl-2-methyl-3-cyclohexen-4-yl)pyridinebis(dimethylglyoximato)cobalt(III)(158678-12-7)

Safety Data

• Hazardous Substances Data: 158678-12-7(Hazardous Substances Data)

Upstream product

• 54863-29-5 2-(trimethylacetoxy)-3,4-pentadiene 
• 17615-18-8 4-acetoxy-1,2-pentadiene 
• 110-86-1 pyridine 
• 2206-23-7 pent-3-en-1-yne 
• 6147-53-1 cobalt(II) diacetate tetrahydrate 
• 78-94-4 methyl vinyl ketone 
• 95-45-4 butane-2,3-dione dioxime 

Relevant articles and documents

Simple preparation of cobaloxime dienyl complexes and their exo selective Diels-Alder cycloadducts. Progress toward transition metal-mediated Diels-Alder reactions which are catalytic in metal dienyl complex

A new method for the synthesis of cobaloxime dienyl complexes (cobaloxime=pyridine(dimethylglyoxime)2Co) which involves a zinc-mediated hydrocobaltation of enynes is reported. Use of this dienyl complex synthesis method allows subsequent Diels-Alder reactions of these complexes to be accomplished without isolation of the dienyl complexes. A new silane-based cobaloxime-substituted cycloadduct demetallation protocol is then reported which provides Diels-Alder cycloadducts and cobalt complexes which have been recycled into the zinc-mediated dienyl complex synthesis.