15872-89-6Relevant academic research and scientific papers
Biomass-derived dibasic acids to diesters with inorganic ligand-supported catalyst: synthesis, optimization, characterization
Chen, Zhe,Han, Sheng,Lu, Deli,Xu, Yumeng
, (2021/08/23)
Several attempts have been made to obtain aliphatic dicarboxylic diesters from esterification reaction to develop the biomass-derived platform molecules and green manufacturing processes. In this paper, Na3(H2O)6[AlMo6O18(OH)6], an Anderson-type polyoxometalate, firstly, was reported as a catalyst for diester synthesis from dicarboxylic acid to diester which showed an well productivity and selectivity characterized by 1H and 13C. Response surface methodology (RSM) integrated with the desirability function approach was used to determine the best operative conditions, and the optimal reaction parameters for maximum dipropyl succinate yield (77 ± 2.5%) were identified as 1.19?mol.% catalyst loading, 4.9:1 propanol/succinic acid ratio, 113?°C, and 9.6?h. Three batches of tests were carried for catalyst recycling with 78–75% yield even after 6 cycles of esterification. In addition, the substrate carbon chain was increased for investigation of substrate scope achieving satisfactory results and all products were characterized by 1H and 13C nuclear magnetic resonance spectroscopy.
By using low-temperature co- melt solvent a method of catalytic ester (by machine translation)
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Paragraph 0054; 0055, (2017/01/17)
The invention discloses a method of utilizing low-temperature co- melt solvent catalytic ester method, will be 0.05-0.5 mole of sharemelt solvent of low-temperature co-preprocessing, 1-5 mole of share alcohol and 1-10 mole of share of acid in the reaction vessel, stirring and heating, 25-200 ° C reaction under 2-96h, then the reaction fluid settlement , liquid, organic is accepted after passing an examination the level , get the esterification reaction products of the; reaction after the treatment and recovery of low-temperature co- melt solvent the preprocessing, can be reused. This invention utilizes the easy preparation of low-temperature co- melt solvent the preprocessing of catalytic esterification reaction, the reaction front is homogeneous, can be formed after the reaction of the two-phase reaction in the process of direct dehydration, without adding other dehydrating agent, has the advantages of simple operation, the reaction efficiency is high, corrosion of small equipment, less side reactions, the product quality is good, no pollution to the environment, and the like, it has broad application prospects. (by machine translation)
