15875-61-3

Basic information

• Product Name: 1H-Indene-1,3(2H)-dione, 2-[(2-nitrophenyl)methylene]-
• Synonyms: 2-[(2-nitrophenyl)methylene]-1H-indene-1,3(2H)-dione
• CAS NO: 15875-61-3
• Molecular Formula: C₁₆H₉NO₄
• Molecular Weight: 279.25
• Mol File: 15875-61-3.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1H-Indene-1,3(2H)-dione, 2-[(2-nitrophenyl)methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indene-1,3(2H)-dione, 2-[(2-nitrophenyl)methylene]-(15875-61-3)
• EPA Substance Registry System: 1H-Indene-1,3(2H)-dione, 2-[(2-nitrophenyl)methylene]-(15875-61-3)

Safety Data

• Hazardous Substances Data: 15875-61-3(Hazardous Substances Data)

Upstream product

• 117560-06-2 3-phenyliodonio-1,2,4-trioxo-1,2,3,4-tetrahydronaphthalenide 
• 552-89-6 2-nitro-benzaldehyde 
• 606-23-5 1H-indene-1,3(2H)-dione 

Downstream Products

• 103966-54-7 (2R,3S)-2-Benzoyl-3-(2-nitro-phenyl)-2,3-dihydro-indeno[1,2-b]furan-4-one 
• 81840-56-4 3-ethoxycarbonyl-2-methyl-4-(2-nitrophenyl)-5-oxo-1,4-dihydroindeno<1,2-b>pyridine 

Relevant articles and documents

Styryl and functionalized aryl derivatives of lawsone through metal-free cross-coupling of its BF3-activated phenyliodonium ylide with cinnamaldehydes and arylaldehydes

Phenyliodonium ylide of lawsone activated with BF3?Et2O reacts with cinnamaldehydes to afford 2-hydroxy-3-styryl-1,4-naphthoquinones in good to excellent yields and relatively high level of stereospecificity through deformylation of the aldehydes. The product yield is diminished with a methoxy substituted cinnamaldehyde and becomes zero with a dimethoxy substituted substrate giving rise to another product, 2-hydroxy-3-aryl-1,4-naphthoquinone. The reaction of the same ylide with salicylic aldehydes forms 2-hydroxy-3-(2-hydroxyaryl)-1,4-naphthoquinones and/or benzo[d]naphtha[2,1-b]furano-5,6-diones, depending on the reaction conditions applied. Plausible reaction mechanisms explaining the formation of these products are proposed. The products showed potent antioxidant activity and inhibited lipoxygenase.

Clean synthesis of 2-arylideneindan-1,3-diones in water

A high-yield synthesis of 2-arylideneindan-1,3-diones in water was achieved by the Knoevenagel condensation of indan-1,3-dione with aromatic aldehydes at ambient temperature avoiding the addition of any catalyst. The procedure is simple, efficient, as wel

Reaction of selenonium monoketoylides with 2-arylideneindanediones

The reaction of selenonium monoketoylide with 2-arylidene-1,3-indanediones was investigated.Dihydrofurans with various structures or 2-(α-phenacylarylidene)-1,3-indanediones are formed, depending on the nature of the arylidene group.