15875-88-4Relevant academic research and scientific papers
Synthesis of esters from aldehydes or carboxylic acids with dichloromethane, dichloroethane or dichloropropane under mild conditions
Lin, Feng,Feng, Qiang,Cui, Xiuling,Song, Qiuling
, p. 20246 - 20253 (2013/11/06)
Dichloromethane (DCM) as a C1 source has been discovered: methylene diesters from DCM and carboxylic acids or aldehydes with TBHP in water were efficiently synthesized. The reactions proceed under mild conditions and afford both aliphatic and aromatic met
Transition-metal-free aerobic oxidative cleavage of C-C bonds in α-hydroxy ketones and mechanistic insight to the reaction pathway
Liu, Hui,Dong, Chao,Zhang, Zeguang,Wu, Peiyu,Jiang, Xuefeng
supporting information, p. 12570 - 12574 (2013/02/22)
Clear cut: For the title reaction, O2, the ideal oxidant, was used as the only oxidizing reagent. The dimer intermediate (see scheme) and isotopic labeling control experiments with 18O2 partially disclosed the reaction mec
