15876-31-0

Basic information

• Product Name: Cyclohexane,1-(1,1-dimethylethyl)-4-methoxy-trans-
• Synonyms: Cyclohexane,1-(1,1-dimethylethyl)-4-methoxy-trans-
• CAS NO: 15876-31-0
• Molecular Formula: C₁₁H₂₂O
• Molecular Weight: 170.29
• Mol File: 15876-31-0.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexane,1-(1,1-dimethylethyl)-4-methoxy-trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane,1-(1,1-dimethylethyl)-4-methoxy-trans-(15876-31-0)
• EPA Substance Registry System: Cyclohexane,1-(1,1-dimethylethyl)-4-methoxy-trans-(15876-31-0)

Safety Data

• Hazardous Substances Data: 15876-31-0(Hazardous Substances Data)

Usage

InChI:InChI=1S/C11H22O/c1-11(2,3)9-5-7-10(12-4)8-6-9/h9-10H,5-8H2,1-4H3/t9-,10-

Upstream product

• 186581-53-3 diazomethane 
• 21862-63-5 trans-4-tert-butylcyclohexanol 
• 98-52-2 4-(1,1-dimethylethyl)-cyclohexanol 
• 74-88-4 methyl iodide 
• 944-19-4 4-tert-butyl-1,1-dimethoxy-cyclohexane 
• 865-50-9 iodomethane-d3 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 3178-22-1 tert-butylcyclohexane 
• 81256-40-8 (4-tert-Butyl-cyclohexyloxy)-triethyl-silane 
• 2228-98-0 4-tert-butylcylohexene 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 3315-60-4 methanolate 
• 1900-69-2 trans-4-tert-butylcyclohexyl acetate 
• 1310559-71-7 4-(t-butyl)-1-methoxy-N-(perfluorophenyl)cyclohexanecarboxamide 
• 1310559-74-0 trans-2-(4-(t-butyl)cyclohexyloxy)-N-(pentafluorophenyl)acetamide 

Relevant articles and documents

Experimental studies of the anomeric effect. Part III. Rotameric preferences about the exo-cyclic c2-x bond in equatorial and axial 2-methoxy-and 2-methylamino-tetrahydropyrans

Values of3 J(CC), 3J(CH), 4J(CH) and 3J(HH), supported by n.O.enhancements, in nmr spectra of 2-methoxy- and 2-methyl-amino-tetrahydropyrans, point to a very strong preference for rotamers in which an exo-cyclic heteroatom lone pair is antiperiplanar to the endo-cyclic C2-O bond ("endo-anomeric effect").

TRIMETHYLSILYL TRIFLATE IN ORGANIC SYNTHESIS

Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media.The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.