158761-03-6Relevant articles and documents
A short synthesis of Mniopetal F?
Jauch, Johann
, p. 473 - 476 (2007/10/03)
The first total synthesis of Mniopetal F in fourteen steps is reported. Key steps are a new and highly diastereoselective lithium phenylselenide-induced Baylis-Hillman reaction with Feringa's butenolide, an endo-selective intramolecular Diels-Alder reaction (IMDA), inversion of a highly hindered secondary alcohol and a new variant of the Parikh-Doering oxidation.