1587688-92-3Relevant academic research and scientific papers
Pd(0)-Catalyzed radical aryldifluoromethylation of activated alkenes
Wang, Jian-Yong,Su, Yi-Ming,Yin, Feng,Bao, Yan,Zhang, Xin,Xu, Yue-Ming,Wang, Xi-Sheng
supporting information, p. 4108 - 4111 (2014/04/03)
A Pd(0)-catalyzed intramolecular aryldifluoromethylation of activated alkenes under mild reaction conditions has been developed. This reaction provides a new method for construction of a variety of difluoromethylated oxindoles. Mechanistic investigations indicate that a difluoromethyl radical, which was triggered by Pd(0), initiated the cascade sequence through an addition to the alkene. This journal is the Partner Organisations 2014.
