158780-52-0

Upstream product

• 158780-50-8 (3aR,4S,6S,6aS)-4-Allyl-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole-4-carboxylic acid methyl ester 

Downstream Products

• 161099-08-7 (3aR,4R,6S,6aS)-4-Allyl-6-benzyloxy-4-methoxymethoxymethyl-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole 
• 848842-22-8 benzyl 5-O-acetyl-2,3-O-isopropylidene-4-C-(2-propenyl)-α-D-lyxofuranoside 
• 848842-25-1 benzyl 5-O-acetyl-2,3-O-isopropylidene-4-C-(2,3-diacetyloxy-3-phenylthiopropyl)-α-D-lyxofuranoside 
• 848842-24-0 benzyl 5-O-acetyl-2,3-O-isopropylidene-4-C-(2-acetyloxy-3-phenylthiopropyl)-α-D-lyxofuranoside 
• 848842-23-9 benzyl 5-O-acetyl-2,3-O-isopropylidene-4-C-(2,3-epoxypropyl)-α-D-lyxofuranoside 
• 205864-59-1 4-((2R,3R,4R,5R)-5-Allyloxy-3,4-bis-benzyloxy-2-methoxymethoxymethyl-tetrahydro-furan-2-ylmethyl)-2,2-dimethyl-[1,3]dioxolane 

Relevant academic research and scientific papers

Synthesis of novel types of divalent saccharide structures by a ketene acetal Claisen rearrangement

A simple allyl uronate was rearranged to give the branched product, which in turn could be transformed into a spiro-annellated bicyclic compound. More complex allyl uronates of d-and l-arabinose were rearranged to give novel methylene-bridged dimeric sacc

Synthetic Studies Towards the Squalestatins and Zaragozic Acids.

A synthesis of a model core system (18) of the squalestatins and zaragozic acids has been achieved from D-mannose.The key steps involve an Ireland-Claisen rearrangement of the allyl ester 5 and a stereoselective epoxidation of the furanoid glycal 12 with

A Synthetic Approach to the Squalestatins and Zaragozic Acids: Introduction of the C5 Stereocentre via an Ester-Enolate Claisen Rearrangement. The X-Ray Crystal Structure of an Intermediate

In an overall plan to synthesize the anti-cholesterol agents the squalestatins and zaragozic acids, introduction of the C5 stereochemistry was achieved via an Ireland-Claisen rearrangement of the allyl ester (7) followed by methylation, which gives the es