158818-92-9

Upstream product

• 80738-62-1 2-O-acetyl-3,4,6-tri-O-benzyl-1,5-anhydro-D-arabino-hex-1-enitol 
• 55659-53-5 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-glucopyranosyl bromide 
• 38081-38-8 3,4,6-tri-O-acetyl-1,2-O-<1-(exo-ethoxy)ethylidene>-α-D-glucopyranose 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 158852-31-4 3,4,6-tri-O-benzyl-1,2-O-(exo-ethoxyethylidene)-α-D-glucopyranose 

Downstream Products

• 136824-12-9 methyl 3,4,6-tri-O-benzyl-β-D-mannopyranosyl-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 98925-55-4 (2S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-((2R,3R,4S,5R,6S)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-dihydro-pyran-3,3-diol 
• 158818-96-3 phenyl 3,4,6-tri-O-benzyl-1-thio-β-D-arabino-hexopyranosid-2-ulose 
• 158818-97-4 isopropyl 3,4,6-tri-O-benzyl-β-D-arabino-hexopyranosid-2-ulose 
• 158818-95-2 ethyl 3,4,6-tri-O-benzyl-1-thio-β-D-arabino-hexopyranosid-2-ulose 
• 40246-34-2 (2R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-ylmethoxy)-dihydro-pyran-3-one 
• 112330-11-7 (3,4,6-tri-O-benzyI-β-D-mannopyranosyl)-(1→6)-1,2,3,4-di-O-isoprpopylidene-α-D-galactopyranoside 

Relevant academic research and scientific papers

Total Synthesis and Absolute Configuration of Simpotentin, a Potentiator of Amphotericin B Activity

The total synthesis of simpotentin (1), a new potentiator of amphotericin B activity against Candida albicans, was achieved. Our research results enabled the access of all stereoisomers of 1 and the elucidation of the unknown absolute configuration of 1.

3,4,6-Tri-O-benzyl-α-D-arabino-hexopyranos-2-ulosyl Bromide: A Versatile Glycosyl Donor for the Efficient Generation of β-D-Mannopyranosidic Linkages

An expedient four-step sequence is described for the conversion of acetobromoglucose into the title 2-oxohexosyl ("ulosyl") bromide 4.Due to its O-benzyl protection, 4 is considerably more reactive than its acylated analogs 1-3: Ag2CO3-promoted glycosidat