15884-61-4Relevant academic research and scientific papers
Resonance Raman observation of surface carbonyl groups on carbon electrodes following dinitrophenylhydrazine derivatization
Fryling, Mark A.,Zhao, Jun,McCreery, Richard L.
, p. 967 - 975 (2007/10/02)
Dinitrophenylhydrazine (DNPH) was used to form hydrazone derivatives of carbonyl groups on glassy carbon (GC) and pyrolytic graphite surfaces. The DNPH adducts of benzoquinone and acetone have cross sections of 488 nm, much larger than those of either DNP
Oxidative behaviours and relative reactivities of some α-hydroxy acids towards bromate ion in hydrochloric acid medium
Gupta, Kalyan Kali Sen,Banerjee, Amalendu,Chatterjee, Hrishikesh
, p. 5323 - 5330 (2007/10/02)
The oxidation kinetics of some α-hydroxy acids by potassium bromate in dilute hydrochloric acid medium have been studied. The reactions are first order with respect to bromate ion. α-hydroxy acid and hydrogen ion concentrations. The reaction rate is governed by two factors : (i) the ease with which the protonated hydroxy acid is produced and (ii) the stability of the intermediate (1:1) bromate ester. The activation parameters of the reactions have been compared. The plausible mechanism of the oxidation process has been suggested. The reactivity of the α-hydroxy acids towards bromate ion are as follows: 9-hydroxy-9-carboxy fluorene> atrolactic acid> mandelic acid> benzilic acid> α-hydroxyisobutyric acid> lactic acid> glycolic acid.
Ketene. Part 24. The Reactions of N-(Fluoren-9-ylidene)methylamine N-Oxide with Dimethylketene and Ketene
Gettins, Anthony F.,Hashi,Nur A.,Stokes, David P.,Taylor, Giles A.,Wyse, Kevin J.
, p. 2501 - 2504 (2007/10/02)
The principal products of the reaction of the N-methylnitrone (1a) with dimethylketene have been identified as the dioxolane derivative (6) and its hydrolysis products (7).Fluoren-9-yl isocyanide appears to be an intermediate in this reaction.Ketene reacts with nitrone (1a) and its N-ethyl and N-isopropyl analogues to give the cyclobutanedione (15) as the only isolated product.Compound (15) has been synthesized from fluoren-9-ylidenemalonic acid.
Oxidation of Fluoren-9-ols by 1-Chlorobenzotriazole - A Kinetic and Mechanistic Study
Kuselan, P.,Venkatasubramanian, N.
, p. 1095 - 1097 (2007/10/02)
The kinetics of oxidation of fluoren-9-ol ans five substituted fluoren-9-ols and of fluoren-9-ol-α-d by 1-chlorobenzotriazole have been studied.The reactions follow a simple rate law.The reaction exhibits a kinetic isotope effect of 1.51 and has a Hammett
