158867-55-1

Basic information

• Product Name: (2R,4aS,5aS,8R,9aR,9bR)-1-perhydro-2,8-diphenyl-2H,5H,8H-bis<1,3>dioxino<5,4-b:4',5'-d>pyrrolidine
• Synonyms: (2R,4aS,5aS,8R,9aR,9bR)-1-perhydro-2,8-diphenyl-2H,5H,8H-bis<1,3>dioxino<5,4-b:4',5'-d>pyrrolidine
• CAS NO: 158867-55-1
• Molecular Weight: 682.794
• Mol File: 158867-55-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,4aS,5aS,8R,9aR,9bR)-1-perhydro-2,8-diphenyl-2H,5H,8H-bis<1,3>dioxino<5,4-b:4',5'-d>pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4aS,5aS,8R,9aR,9bR)-1-perhydro-2,8-diphenyl-2H,5H,8H-bis<1,3>dioxino<5,4-b:4',5'-d>pyrrolidine(158867-55-1)
• EPA Substance Registry System: (2R,4aS,5aS,8R,9aR,9bR)-1-perhydro-2,8-diphenyl-2H,5H,8H-bis<1,3>dioxino<5,4-b:4',5'-d>pyrrolidine(158867-55-1)

Safety Data

• Hazardous Substances Data: 158867-55-1(Hazardous Substances Data)

Upstream product

• 101294-01-3 4-methyl-N-(3-oxo-3-phenyl-propyl)benzenesulfonamide 
• 158867-57-3 N-(3-hydroxy-3-phenylpropyl)-4-methyl-benzenesulfonamide 
• 158867-60-8 2-(trimethylsilyl)ethyl N-(2-benzoylethyl)-N-tosylglycinate 
• 158867-59-5 2-(trimethylsilyl)ethyl N-(3-hydroxy-3-phenylpropyl)-N-tosylglycinate 
• 26189-59-3 1-chloro-1-(dimethylamino)-2-methyl-1-propene 
• 133443-76-2 (2R,4aS,5aS,8R,9aR,9bR)-Perhydro-2,8-diphenyl-2H,5H,8H-bis<1,3>dioxino<5,4-b:4',5'-d>pyrrole 
• 158867-61-9 N-(2-benzoylethyl)-N-tosylglycine 

Relevant articles and documents

Asymmetric synthesis of 3-hydroxyprolines by photocyclization of N-(2-benzoylethyl)glycinamides

The chiral N-(2-benzoylethyl)-N-tosylglycinamides 1a-c were prepared from the C2-symmetric pyrrolidines 5a-c. Irradiation of these ketones 1a-c gave cis-3-hydroxyprolinamides 10-12 in moderate to good yields (Scheme 3). The de of the photocycli