158883-07-9

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 1054658-70-6 (2S,3S,4R,5R,6R)-2,4,5-Tris-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-hydroxy-cyclohexanone 

Downstream Products

• 1027904-54-6 (2S,4aR,5R,6S,8R,8aS)-5,6,8-Tris-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxin-7-one 
• 139402-99-6 (1S,2S,3R,4S,5R,6R)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexyl methanesulfonate 
• 906748-02-5 (1S,2R,3S,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]cyclohexanol 
• 158883-08-0 (2S,4aR,5R,6S,7R,8R,8aS)-5,6,7,8-Tetrakis-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxine 
• 214411-20-8 (1S,2S,3R,4S,5R,6R)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]cyclohexyl methanesulfonate 

Relevant academic research and scientific papers

A Divergent Route for a Total Synthesis of Cyclophellitol and Epicyclophellitol from a Oxabicyclic Glycoside Prepared from D-Glucal

D-Glucal has been used for syntheses of Tatsuta's penultimate intermediate for cyclophellitol and epicyclophellitol via a 6-exo-trig radical cyclization of 2-deoxy-2-iodo-6-alkynyl glycoside, the diastereomeric mixture produced thereby being separated into two sets, each of which leads to one or other target materials.