214411-20-8

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 906748-02-5 (1S,2R,3S,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]cyclohexanol 
• 158883-07-9 (2S,4aR,5R,6R,7S,8S,8aS)-5,6,8-Tris-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol 
• 158883-08-0 (2S,4aR,5R,6S,7R,8R,8aS)-5,6,7,8-Tetrakis-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxine 
• 1027904-54-6 (2S,4aR,5R,6S,8R,8aS)-5,6,8-Tris-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxin-7-one 
• 1054658-70-6 (2S,3S,4R,5R,6R)-2,4,5-Tris-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-hydroxy-cyclohexanone 
• 214203-48-2 1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene 
• 214203-47-1 (1R,2S,3R,4R,5S,6R)-2,3,4-tris(benzyloxy)-6-(hydroxymethyl)-5-[(4-methoxybenzyl)oxy]cyclohexanol 
• 906641-07-4 (1S,2R,3S,4S,5R,6R)-2,3,4-tris(benzyloxy)-5-[(4-methoxybenzyl)oxy]-7-oxabicyclo[4.1.0]heptane 
• 606930-14-7 (2S,3R,4S)-2,3,4-tris-benzyloxy-5-hydroxycyclohexan-1-one 
• 85716-44-5 methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside 
• 133218-74-3 4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol 
• 102997-58-0 (1R,2R,3S)-tris(phenylmethoxy)-6S-hydroxy-cyclohex-4-ene 
• 85798-11-4 (4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one 

Downstream Products

• 139402-99-6 (1S,2S,3R,4S,5R,6R)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexyl methanesulfonate 

Relevant academic research and scientific papers

Synthesis of cyclophellitol utilizing a palladium chloride mediated-ferrier-II rearrangement

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl 2.

An efficient synthesis of cyclophellitol utilizing unusual regioselectivity of oxirane ring opening with Mes2BCH2Li

Cyclophellitol has been synthesized from 5,6-enoglucoside efficiently. The carbacyclic skeleton was constructed through a Ferrier reaction mediated by PdCl2. The regioselectivity on the oxirane ring opening with Mes2BCH2Li

A Divergent Route for a Total Synthesis of Cyclophellitol and Epicyclophellitol from a Oxabicyclic Glycoside Prepared from D-Glucal

D-Glucal has been used for syntheses of Tatsuta's penultimate intermediate for cyclophellitol and epicyclophellitol via a 6-exo-trig radical cyclization of 2-deoxy-2-iodo-6-alkynyl glycoside, the diastereomeric mixture produced thereby being separated into two sets, each of which leads to one or other target materials.