596815-62-2Relevant articles and documents
Copper(ii)-catalyzed protoboration of allenes in aqueous media and open air
Nekvinda, Jan,Santos, Webster L.,Snead, Russell F.
, p. 14925 - 14931 (2021)
A method has been developed for the facile Cu(ii)-catalyzed protoboration of monosubstituted allenes in aqueous media under atmospheric conditions. The reaction occurs site selectively, favoring internal alkene protoboration to afford 1,1-disubstituted vinylboronic acid derivatives (up to 93?:?7) with modest to good yields. The method has been applied to a variety of phenylallene derivatives as well as alkyl-substituted allenes. This journal is