158961-76-3Relevant academic research and scientific papers
Synthesis of a Bis-Manganese Water Splitting Complex
Watkinson, Michael,Whiting, Andrew,McAuliffe, Charles A.
, p. 2141 - 2142 (1994)
Complex 8 has been prepared by an efficient one-step manganese-templated condensation/macrocyclisation; upon irradiation using visible light in water in the presence of p-benzoquinone, complex 8 demonstrates the ability to split water.
Enantioselective CD analysis of amino acids based on chiral amplification with a stereodynamic probe
Ghosn, Marwan W.,Wolf, Christian
supporting information; experimental part, p. 3989 - 3994 (2010/07/06)
The condensation between stereolabile 1,8-bis(3′-formyl-4′-hydroxyphenyl)naphthalene, 1, and two amino acid molecules results in the formation of chiral diimines exhibiting strong CD signals. This reaction has been used to develop a chiroptical sensing me
Chiral amplification with a stereodynamic triaryl probe: Assignment of the absolute configuration and enantiomeric excess of amino alcohols
Ghosn, Marwan W.,Wolf, Christian
supporting information; experimental part, p. 16360 - 16361 (2010/01/29)
(Figure Presented) A stereodynamic, axially chiral triaryl probe is locked into a single conformation upon condensation with two amino alcohol substrates. The well-defined chiral amplification in the diimines formed results in intense Cotton effects at high wavelengths that can be used for in situ CD analysis of the absolute configuration and ee of cyclic and acyclic substrates.
Pillared salicylaldehyde derivatives as building blocks for the design of cofacial salen-type ligands
Sabater, Laurent,Guillot, Regis,Aukauloo, Ally
, p. 2923 - 2926 (2007/10/03)
The syntheses of pillared salicylaldehyde derivatives on a naphthalene block are reported. These compounds can be considered as building blocks for the elaboration of cofacial salen-typed ligands. The X-ray structure of a dinuclear manganese(III) complex is described, supporting our strategy to build topologically controlled multinuclear metal complexes.
