15898-67-6Relevant articles and documents
In situ generation and nucleophilic capture of 1,n-dial equivalents from 1,n-dioates (α,ω-diesters)
Hoye, Thomas R.,Kopel, Lucas C.,Ryba, Troy D.
, p. 1572 - 1574 (2006)
A procedure is described for the in situ generation of functional equivalents of glutaric, succinic, and malonic dialdehydes. DIBAL-H reduction of the corresponding 1,n-dioates followed by in situ addition of a nucleophilic trapping agent allows for one-p
A highly nucleophilic multifunctional chiral phosphane-catalyzed asymmetric intramolecular rauhut-currier reaction
Zhang, Xiao-Nan,Shi, Min
supporting information, p. 6271 - 6279 (2013/01/15)
An asymmetric variant of the intramolecular Rauhut-Currier (RC) reaction can be achieved using a highly nucleophilic multifunctional chiral phosphane; the corresponding cyclopentene and cyclohexene derivatives are produced in moderate to good yields and w
Effect of phase transfer chemistry, segmented fluid flow, and sonication on the synthesis of cinnamic esters
Riccaboni, Mauro,La Porta, Elena,Martorana, Andrea,Attanasio, Roberta
experimental part, p. 4032 - 4039 (2010/07/06)
Wittig reaction under Phase Transfer conditions was performed in a flow reaction system. Different bases, aldehydes, phosphonium salts, and flow reaction parameters were investigated, in absence of a phase transfert catalyst. An improvement of the reaction outcome (yield and reaction time) was achieved through the immersion of the reactor into an ultrasound bath.
