15910-85-7

Upstream product

• 15910-50-6 6-Methoxy-1,3,6-tri-tert-butyl-bicyclo<3.1.0>hex-3-en-2-on 
• 15910-49-3 2,4,6-tri-tert-butyl-4-methoxy-2,5-cyclohexadienone 

Downstream Products

• 26755-37-3 1,5-Di-tert-butyl-2-methoxy-4-(2-methyl-propenyl)-benzene 
• 15910-86-8 3,6-Di-tert.-butyl-guajacol 

Relevant academic research and scientific papers

EFFICIENCY FOR SOLID-STATE PHOTOREARRANGEMENT OF 2,5-CYCLOHEXADIENONES

Visible light irradiation of 2,5-cyclohexadienones 1a and 1b in the solid state resulted in quantitative transformation into two isomeric lumiketones.The reaction was more efficient for bulky 1a (Φ = 0.46) than for less bulky 1b (Φ = 0.28).

SOLID STATE PHOTOCHEMISTRY OF 2,5-CYCLOHEXADIENONES

Santonin, a 2,5-cyclohexadienone, is known to undergo photorearrangement to lumisantonin in solution but to a cyclopentadienone in the solid state in accordance with the topochemical principle of a minimum of atomic movement in crystal lattice.In contrast