15910-86-8

Upstream product

• 15910-49-3 2,4,6-tri-tert-butyl-4-methoxy-2,5-cyclohexadienone 
• 15910-50-6 6-Methoxy-1,3,6-tri-tert-butyl-bicyclo<3.1.0>hex-3-en-2-on 
• 15910-85-7 3-Methoxy-2,4,6-tri-tert-butyl-cyclohexa-2,5-dien-1-on 
• 489-01-0 2,6-Di-t-butyl-4-methoxyphenol 

Downstream Products

• 23803-85-2 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone 
• 34105-76-5 3,5-di-tert-butyl-1,2-benzoquinone 

Relevant academic research and scientific papers

EFFICIENCY FOR SOLID-STATE PHOTOREARRANGEMENT OF 2,5-CYCLOHEXADIENONES

Visible light irradiation of 2,5-cyclohexadienones 1a and 1b in the solid state resulted in quantitative transformation into two isomeric lumiketones.The reaction was more efficient for bulky 1a (Φ = 0.46) than for less bulky 1b (Φ = 0.28).

SOLID STATE PHOTOCHEMISTRY OF 2,5-CYCLOHEXADIENONES

Santonin, a 2,5-cyclohexadienone, is known to undergo photorearrangement to lumisantonin in solution but to a cyclopentadienone in the solid state in accordance with the topochemical principle of a minimum of atomic movement in crystal lattice.In contrast