159123-26-9

Basic information

• Product Name: [P(CH₂Ph)Ph₃][AuCl(mesityl)]
• CAS NO: 159123-26-9
• Molecular Weight: 705.029
• Mol File: 159123-26-9.mol

Chemical Properties

• CAS DataBase Reference: [P(CH₂Ph)Ph₃][AuCl(mesityl)](CAS DataBase Reference)
• NIST Chemistry Reference: [P(CH₂Ph)Ph₃][AuCl(mesityl)](159123-26-9)
• EPA Substance Registry System: [P(CH₂Ph)Ph₃][AuCl(mesityl)](159123-26-9)

Safety Data

• Hazardous Substances Data: 159123-26-9(Hazardous Substances Data)

Upstream product

• 2633-66-1 2-mesitylmagnesium bromide 
• 159123-24-7 [Au(mesityl)(AsPh₃)] 
• 1100-88-5 benzyltriphenylphosphonium chloride 

Relevant articles and documents

Mesitylgold Complexes: Synthesis and Reactivity; Crystal Structure of 2>2 (mes = mesityl, tht = tetrahydrothiophene)

The complex reacted with MgBr(mes) (mes = mesityl) to give the corresponding gold(I) derivative , which undergoes substitution reactions with neutral ligands to give the neutral complexes (L = Ph2PCH2PPh2, PPh3 or PPh2Me) or with QX to afford anionic complexes Q .The latter reacted with X2 (X = Cl or Br) to give gold(III) complexes, Q .The reaction of with afforded n>n (L = PPh3, n = 1; L = tht, n = 2).The structure of 2>2 has been determined by a single-crystal X-ray diffraction study, which shows an Au-Ag distance of 2.8245(6) Angstroem.