159160-19-7Relevant academic research and scientific papers
Ionic complexes [Au2(P-P)2][Co(CO)4]2 as intermediates in the synthesis of compounds containing a Co2 Au2 core
Pons, Angels,Rossell, Oriol,Seco, Miquel,Solans, Xavier,Font-Bardia, Merce
, p. 177 - 182 (2007/10/03)
The pathway for the formation of [Co2 Au2(CO)6( μ-dppm)2] (3) from dppm and [{(CO)4CoAu}2( μ-dppm)] (2a) seems to involve the intermediate complex [Au2( μ-dppm)2][Co(C
[Co2Au2(CO)6(μ-dppm)2]: A 10-membered cycle compound including a novel Co2Au2 Z-skew frame geometry
Pons, Angels,Rossell, Oriol,Seco, Miquel,Perales, Aurea
, p. 555 - 557 (2008/10/08)
The substitution of two carbonyl groups by a dppm ligand in the complex [{(CO)4CoAu}2(dppm)] (1) causes permutation in the metal skeleton sequence, giving the novel complex [Co2Au2(CO)6(μ-dppm)2] (3) characterized by X-ray crystallography. Crystals of 3 are monoclinic, space group Cc with unit cell parameters of a = 18.834(1) A?, b = 16.257(1) A?, c = 20.366(2) A?, β = 112.350(3)°, Z = 4, and V = 6235(11) A?3. A mechanism for the formation of 3 is suggested.
