159161-03-2Relevant articles and documents
Electron-poor pentafluorophenyl-substituted PCP - Palladium pincer complexes
Chase, Preston A.,Gagliardo, Marcella,Lutz, Martin,Spek, Anthony L.,Van Klink, Gerard P. M.,Van Koten, Gerard
, p. 2016 - 2019 (2005)
A novel fluoroaryl-substituted PCP ligand has been synthesized and used to generate the corresponding Pd complexes. The bonding of the fluoroaryl phosphine has been investigated by X-ray crystallography, NMR spectroscopy, and a competition experiment, which indicate that the ligand is sterically comparable to its well-known phenyl analogue but clearly imparts significant electronic differences to the metal center.