Organometallics p. 2016 - 2019 (2005)
Update date:2022-08-04
Topics:
Chase, Preston A.
Gagliardo, Marcella
Lutz, Martin
Spek, Anthony L.
Van Klink, Gerard P. M.
Van Koten, Gerard
A novel fluoroaryl-substituted PCP ligand has been synthesized and used to generate the corresponding Pd complexes. The bonding of the fluoroaryl phosphine has been investigated by X-ray crystallography, NMR spectroscopy, and a competition experiment, which indicate that the ligand is sterically comparable to its well-known phenyl analogue but clearly imparts significant electronic differences to the metal center.
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(2014)
