159298-92-7

Basic information

• Product Name: 1-(4-bromophenyl)ethyl methanesulfonate
• Synonyms: 1-(4-bromophenyl)ethyl methanesulfonate
• CAS NO: 159298-92-7
• Molecular Weight: 279.155
• Mol File: 159298-92-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(4-bromophenyl)ethyl methanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-bromophenyl)ethyl methanesulfonate(159298-92-7)
• EPA Substance Registry System: 1-(4-bromophenyl)ethyl methanesulfonate(159298-92-7)

Safety Data

• Hazardous Substances Data: 159298-92-7(Hazardous Substances Data)

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 5391-88-8 1-(4-bromophenyl)ethanol 

Downstream Products

• 1338439-72-7 C₁₆H₁₇Br₂N 
• 257604-11-8 1-(1-azidoethyl)-4-bromobenzene 
• 5391-88-8 1-(4-bromophenyl)ethanol 
• 159298-87-0 1-bromo-4-(1-fluoroethyl)benzene 

Relevant articles and documents

A Lewis acid mediated schmidt reaction of benzylic azide: Synthesis of sterically crowded aromatic tertiary amines

An efficient one-pot synthesis of sterically hindered aromatic tertiary amines through Lewis acid induced intermolecular Schmidt reaction of benzylic azides is described. In the presence of EtAlCl2, benzylic azide underwent a smooth Schmidt reaction to give the corresponding iminium ion, which, upon reduction with NaBH4 in situ, afforded the tertiary amine. The effects of substituents on the aromatic ring and the steric effects of the alkyl side chain have also been studied.