1593215-45-2Relevant academic research and scientific papers
Oxygen and methanol mediated irreversible coordination polymer structural transformation from a 3D Cu(i)-framework to a 1D Cu(ii)-chain
Ge, Jing-Yuan,Wang, Jian-Cheng,Cheng, Jun-Yan,Wang, Peng,Ma, Jian-Ping,Liu, Qi-Kui,Dong, Yu-Bin
, p. 4434 - 4437 (2014)
An interesting irreversible structural transformation visible to the naked-eye occurs when a 3D Cu(i)-polymeric complex Cu2L(NO 3)2(DMF)0.4 (1) is suspended in CH 3OH in air to produce a 1D-Cu(ii) polymeric complex Cu(μ-OCH 3)(L)(NO3) (2) (L = 1,2-bis[4-(pyrimidin-4-yl)phenoxy] ethane). The transformation mechanism from 1 to 2 was also investigated. This journal is the Partner Organisations 2014.
