159347-04-3Relevant academic research and scientific papers
Total Syntheses of (+)- and (-)-Nonactate Esters using Silicon Compounds to Control the Stereochemistry
Fleming, Ian,Ghosh, Sunil K.
, p. 2285 - 2286 (1994)
1,3-Transposition, using the epoxidation of the allylsilane 7, derived from the meso 3,4-disilylated adipate 1, gives the 1,4-related stereocentres of 8-oxo-6-hydroxy-3-dimethyl(tolyl)silylnonanoic acid ethylene acetal 10; two highly stereocontrolled sequences from this common intermediate give methyl (+)-nonactate 13 and benzyl (-)-nonactate 17.
