1594112-87-4 Usage
Uses
Used in Chemical Synthesis:
Trans-bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride is used as a precatalyst for enhancing the rates of various nickel-catalyzed reactions. Its air stability and ease of handling make it a preferred choice over other nickel catalysts, such as Ni(cod)2. The complex maintains high selectivity in these reactions, ensuring the desired products are formed with minimal side reactions.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, trans-bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride can be employed as a catalyst in the synthesis of complex organic molecules, including those with potential therapeutic applications. Its ability to improve reaction rates and selectivity can lead to more efficient production processes and the development of novel drugs.
Used in Material Science:
The complex can also be utilized in the field of material science, where it may serve as a catalyst for the synthesis of advanced materials with specific properties. Its air stability and catalytic efficiency can contribute to the development of new materials with applications in various industries, such as electronics, energy storage, and aerospace.
Used in Environmental Applications:
Trans-bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride can be employed in environmental applications, such as the development of more sustainable chemical processes and the synthesis of environmentally friendly materials. Its catalytic properties can help reduce waste and improve the overall efficiency of chemical reactions, contributing to a more sustainable future.
Check Digit Verification of cas no
The CAS Registry Mumber 1594112-87-4 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,5,9,4,1,1 and 2 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1594112-87:
(9*1)+(8*5)+(7*9)+(6*4)+(5*1)+(4*1)+(3*2)+(2*8)+(1*7)=174
174 % 10 = 4
So 1594112-87-4 is a valid CAS Registry Number.
1594112-87-4Relevant academic research and scientific papers
NICKEL PRE-CATALYSTS AND RELATED COMPOSITIONS AND METHODS
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Page/Page column 40, (2015/05/26)
Described herein are nickel pre-catalysts and related compositions and methods. The nickel pre-catalysts may be activated to form catalysts which may be utilized in organic reactions.
A broadly applicable strategy for entry into homogeneous nickel(0) catalysts from air-stable nickel(II) complexes
Standley, Eric A.,Smith, Stacey J.,Mueller, Peter,Jamison, Timothy F.
supporting information, p. 2012 - 2018 (2014/05/20)
A series of air-stable nickel complexes of the form L2Ni(aryl) X (L = monodentate phosphine, X = Cl, Br) and LNi(aryl)X (L = bis-phosphine) have been synthesized and are presented as a library of precatalysts suitable for a wide variety of nickel-catalyzed transformations. These complexes are easily synthesized from low-cost NiCl2·6H2O or NiBr 2·3H2O and the desired ligand followed by addition of 1 equiv of Grignard reagent. A selection of these complexes were characterized by single-crystal X-ray diffraction, and an analysis of their structural features is provided. A case study of their use as precatalysts for the nickel-catalyzed carbonyl-ene reaction is presented, showing superior reactivity in comparison to reactions using Ni(cod)2. Furthermore, as the precatalysts are all stable to air, no glovebox or inert-atmosphere techniques are required to make use of these complexes for nickel-catalyzed reactions.
