159461-31-1Relevant academic research and scientific papers
2. Tetraethynylethenes: Fully Cross-Conjugated ?-Electron Chromophores and Molecular Scaffolds for All-Carbon Networks and Carbon-Rich Nanomaterials
Anthony, John,Boldi Armen M.,Rubin, Ives,Hobi, Markus,Gramlich, Volker,et al.
, p. 13 - 45 (1995)
The preparation of tetraethynylethene (3,4-diethynylhex-3-ene-1,5-diyne) 1 as well as of a great diversity of differentially mono-, di-, and triprotected derivatives by newly developed synthetic routes is described.These fully cross-conjugated molecules a
Donor-substituted perethynylated dehydroannulenes and radiaannulenes: Acetylenic carbon sheets featuring intense intramolecular charge transfer
Mitzel, Frieder,Boudon, Corinne,Gisselbrecht, Jean-Paul,Seiler, Paul,Gross, Maurice,Diederich, Francois
, p. 1130 - 1157 (2007/10/03)
In this article, we report the preparation of unprecedented φ-conjugated macrocycles (Fig. 1) by acetylenic scaffolding using modular tetraethynylethene (TEE, 3,4-diethynylhex-3-ene-1,5-diyne) building blocks. A novel photochemical access to (Z)-bisdeprot
