159489-36-8

Upstream product

• 93000-11-4 methyl 3-O-benzyl-4,6-O-benzylidene-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 93000-10-3 benzyl ((2R,4aR,6S,7R,8R,8aS)-8-hydroxy-6-methoxy-2-phenyl hexahydropyrano[3,2-d][1,3]dioxin-7-yl)carbamate 
• 87907-35-5 methyl 2--3-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 159489-49-3 {(S)-1-[(3R,4S,6S)-4-Benzyloxy-6-(benzyloxycarbonylamino-methyl)-2-oxo-tetrahydro-pyran-3-ylcarbamoyl]-2-methyl-propyl}-carbamic acid benzyl ester 
• 159489-44-8 {(S)-1-[(2S,3R,4S,6S)-4-Benzyloxy-6-(benzyloxycarbonylamino-methyl)-2-methoxy-tetrahydro-pyran-3-ylcarbamoyl]-2-methyl-propyl}-carbamic acid benzyl ester 
• 159489-39-1 Toluene-4-sulfonic acid (2R,3R,4R,5R,6S)-4-benzyloxy-5-benzyloxycarbonylamino-2-(tert-butoxycarbonylamino-methyl)-6-methoxy-tetrahydro-pyran-3-yl ester 
• 159489-42-6 {(S)-1-[(2S,3R,4S,6S)-4-Benzyloxy-6-(tert-butoxycarbonylamino-methyl)-2-methoxy-tetrahydro-pyran-3-ylcarbamoyl]-2-methyl-propyl}-carbamic acid benzyl ester 
• 159489-38-0 [(2S,3R,4R,5R,6R)-4-Benzyloxy-6-(tert-butoxycarbonylamino-methyl)-5-hydroxy-2-methoxy-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester 
• 159489-40-4 [(2S,3R,4S,6S)-4-Benzyloxy-6-(tert-butoxycarbonylamino-methyl)-2-methoxy-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester 
• 159489-37-9 ((2S,3R,4R,5R,6R)-6-Azidomethyl-4-benzyloxy-5-hydroxy-2-methoxy-tetrahydro-pyran-3-yl)-carbamic acid benzyl ester 

Relevant academic research and scientific papers

The revised structure of the antibiotic Tue 1718 B confirmed by synthesis

The revised structure of the dipeptide antibiotic Tue 1718 B was confirmed by synthesis of two possible diastereoisomers of L-valyl-dihydroxylysine 2. Comparison of the NMR spectra of the synthetic and natural products indicates (2S,3S,5S)- or (2S,3R,5S)-