1595282-10-2Relevant academic research and scientific papers
Copper-catalyzed monoborylation of silylalkynes; Regio- and stereoselective synthesis of (Z)-β-(borylvinyl)silanes
Chae, Yeong Mi,Bae, Jun Sung,Moon, Jong Hun,Lee, Jin Yong,Yun, Jaesook
supporting information, p. 843 - 849 (2014/04/03)
The selective copper-catalyzed borylation of silylalkynes in the presence of a diboron reagent and methanol produced a variety of (Z)-β-(borylvinyl) silanes. The appropriate use of a selective ligand for copper allows the chemo-, regio-, and stereoselective monoborylation of silylalkynes. The β-regioselectivity of an N-heterocyclic carbene (NHC)-copper catalyst was investigated by DFT calculations.
