159531-03-0

Basic information

• Product Name: ethyl 2-cyclohexylidene-3-(trimethylsilyl)propanoate
• Synonyms: ethyl 2-cyclohexylidene-3-(trimethylsilyl)propanoate
• CAS NO: 159531-03-0
• Molecular Weight: 254.445
• Mol File: 159531-03-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 2-cyclohexylidene-3-(trimethylsilyl)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-cyclohexylidene-3-(trimethylsilyl)propanoate(159531-03-0)
• EPA Substance Registry System: ethyl 2-cyclohexylidene-3-(trimethylsilyl)propanoate(159531-03-0)

Safety Data

• Hazardous Substances Data: 159531-03-0(Hazardous Substances Data)

Upstream product

• 110481-61-3 3-trimethylsilyl-2-diethylphosphonopropionic acid ethyl ester 
• 108-94-1 cyclohexanone 

Downstream Products

• 306326-78-3 4-cyclohexylidene-2-phenyl-5-(trimethylsilyl)pent-1-en-3-ol 
• 306326-59-0 4-cyclohexylidene-2-phenyl-5-(trimethylsilyl)pent-1-en-3-one 
• 306326-77-2 (E)-4-cyclohexylidene-1-phenyl-5-(trimethylsilyl)pent-1-en-3-ol 
• 306326-58-9 (E)-4-cyclohexylidene-1-phenyl-5-(trimethylsilyl)pent-1-en-3-one 
• 306326-75-0 4-cyclohexylidene-2-methyl-5-(trimethylsilyl)pent-1-en-3-ol 
• 264879-05-2 4-cyclohexylidene-2-methyl-5-(trimethylsilyl)pent-1-en-3-one 
• 306326-81-8 (E)-2-cyclohexylidene-1-(trimethylsilyl)hex-4-en-3-ol 
• 306326-74-9 (Z)-2-cyclohexylidene-1-(trimethylsilyl)hex-4-en-3-ol 
• 264879-03-0 (E)-2-cyclohexylidene-1-(trimethylsilyl)hex-4-en-3-one 
• 264879-02-9 (Z)-2-cyclohexylidene-1-(trimethylsilyl)hex-4-en-3-one 
• 159531-09-6 4-cyclohexylidene-5-(trimethylsilyl)pent-1-en-3-ol 
• 159531-12-1 4-cyclohexylidene-5-(trimethylsilyl)pent-1-en-3-one 
• 159531-06-3 2-cyclohexylidene-3-(trimethylsilyl)propanal 
• 306326-67-0 2-cyclohexylidene-3-trimethylsilyl-1-propanol 

Relevant articles and documents

Nazarov cyclization of 4-cycloalkylidene-5-(trimethylsilyl)pent-1-en-3-one derivatives. Synthesis of spiro[4.5]decane, Spiro[4.4]nonane, and Their derivatives

Spiro[4.5]decane and spiro[4.4]nonane ring systems were synthesized by FeCl3-induced Nazarov cyclization of α-(trimethylsilylmethyl)divinyl ketone derivatives. It was found that the double bond position of the product is controlled by the presence/absence of α'-substituent, while trimethylsilyl group is essential to obtain the products in good yields. Spiro[4.4]nonanes having exo-methylene group underwent rearrangement to bicyclo[4.3.0]nonanes. (C) 2000 Elsevier Science Ltd.